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Monolithic carbon aerogels from sol–gel polymerization of phenolic resoles and methylolated melamine

注意:本論文已在《Carbon 》2002,(411): 1645 –1687發表
使用者請注明論文出處
Rui Zhang1 , Yonggen Lu1 , Liang Zhan1 , Xiaoyi Liang1 , Gangping Wu1 ,Licheng Ling1,2
1)Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Southern Taoyuan Road,Yinze Street, Taiyuan 030001, China
2)State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001,


Keywords: Carbon aerogels; Pyrolysis; Adsorption; Density; Porosity

 Carbon aerogels, discovered by Pekala et al. at the beginning of the1990s[1,2], are a novel form of aerogels with low atom number and peculiar properties of electrical conductivity[3], biocompatibility and anti-corrosion by acid or base. Up to now, carbonaerogels rich in micro-, meso- and/or macropores have been synthesized with applications including gas adsorption devices, separators for heavy metals and ions, purification of drinking water, electronic capacitors, fuel cell electrodes, parts for inertial confinement fusion targets, catalyst support and chromato-graphic packing[4,5]. However,costly raw materials and long and tedious processes are the mainobstacles for this novel for mof carbon to be widely accepted in commercial applications, whatever the end use might be. Many efforts have been made to find cheap raw materials\[2,6,7] and to shorten the synthesis routine [8,9].

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